Solar cells made from perovskite have undergone rapid development in recent years. Perovskite is a mineral that has the same crystal structure as calcium-titanium-oxide (CaTiO₃). The yield of this type of solar cell has risen to 22 percent in just a few years. A drawback for the moment, though, is the damaging effect of humidity: water vapor from the atmosphere reacts with the perovskite crystals causing a considerable reduction in the yield over time. This instability is a stumbling block to successful commercialization.

In the findings just published, the researchers have covered the sensitive layer of perovskite with a few atomic layers of aluminum oxide to protect against degradation caused by humidity. These layers are contained within the solar cell, between the layers of perovskite and electric contact.

The researchers opted for aluminum oxide (Al₂O₃) since it can form immediately on any kind of surface. “Although Al₂O₃ has electrically insulating properties, it can still be used as a buffer layer between the semi-conductive perovskite and the conductive contacts by limiting the thickness of the layer to one nanometer or less,” says FOM PhD student and first author Dibyashree Koushik of the TU/e group Plasma and Materials Processing. “Charge carriers can then tunnel electrically through the insulator layer.”

Once manufactured, whereby thin layers were applied with precise composition by atomic layer deposition (ALD), the researchers compared the stability of these cells with identical cells without this layer. The complete cells were not given any further protection against humidity with sealed packaging. Two months after being exposed to a humid atmosphere the cells containing the Al₂O₃ layer reached sixty of seventy percent of their original yield while the reference cells managed only twelve percent.

Bonus

Moreover, the layer boosted the yield from fifteen to eighteen percent. “That was a bonus for us,” leader of the study prof.dr. Ruud Schropp of TU/e says. “We had not expected this and we cannot exactly explain why it is. But we will certainly be investigating.”

Whether the layers will raise the perovskite cell record is difficult to say, according to Schropp. “They are constructed in a completely different way to the simple, scalable structure we chose. But the stability will very probably also increase in those cells.”

The fact that the protective aluminum oxide layer is not incorporated on the outside, as often attempted by other researchers, also makes it possible to apply a broad range of materials on both sides of the solar cell and allows the maximum penetration of light in the perovskite layer and thereby the optimum utilization of electrical current. Schropp: “All this and more robust use of the cells.”

Source: TU/e press team